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BLACK OXIDATION OR PHOSPHATING?

PARAMETERSBLACK OXIDATIONPHOSPHATING
Coating compositioniron (II)-,(III) oxide
  • manganese phosphate 
  • secondary and tertiary
  • also included: secondary and tertiary iron phosphates
Layer thickness0,5 to 2 µm3 to 10 µm (up to approx. 20 µm possible)
fitting problems
  • none, because application/removal are equal
    surface structure is maintained
must be considered beforehand as layer formation from +2 µm to +30 µm
Coating structureamorphousfine crystalline
Other layer properties
  • bend and pressure resistant
  • resistant to solvents and varnishes
  • alkalis do not attack the coating
  • acids attack the coating
  • good sliding properties, reduction of sliding friction during non-cutting work
  • corrosion protection oils and varnishes are taken up well and hardly removed during handling, this ensures high corrosion protection
  • good isolation resistance
  • practically no undermining of damaged coating with rust formation
Coating colourblackgrey to black
Working temperature120 to 150 °Capprox. 80 ± 15 °C
Exposure time5 to 20 minutes8 to 15 minutes
Quantity of chemicals for a 100 l bath formulation50 to 70 kg15 ± 5 kg
Salt spray resistance without oilingup to 30 minutesup to 3 hours
Salt spray resistance with oilingup to 70 hoursup to 200 hours
Rust protection
  • relatively good in dry indoor air
  • poor in humid, acidic air
very good because deep penetration of corrosion protection oil into the pores of the fine crystalline coating is possible
Hazardous materials
  • highly alkaline – strongly corrosive
  • toxic due to sodium nitrite component
corrosive – but only slightly acidic due to nitrate and acid component
Waste waterNeutralisation and detoxificationNeutralisation
Health and safety at workhigh temperatures and high alkalinity require corresponding precautionary measuresweakly acidic, low temperatures
DIN standardDIN 50938DIN EN 12476

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